The Al Pillaring of Clays. Part I. Pillaring with Dilute and Concentrated Al Solutions

Robert A. Schoonheydt1, J. van den Eynde1, H. Tubbax1, H. Leeman, M. Stuyckens1, I. Lenotte1 and W. E. E. Stone2
1 Centrum voor Oppervlaktechemie en Katalyse, Materials Research Center K. U. Leuven, K. Mercierlaan, 92, 3001 Heverlee, Belgium
2 Section Physico-Chimie Minérale (MRAC), UCL, Place Croix du Sud, 2 Boite 18 1348 Louvain-La-Neuve, Belgium

Abstract: Saponite, hectorite, and laponite have been pillared with cationic Al clusters, and special attention has been given to the solution chemistry or Al. Pillared saponite is obtained after exchange with refluxed Al solutions; while for hectorite, Al solutions treated with ammonium acetate give a pillared product with 1.8–1.9 nm spacing and thermal stability up to 873 K. In both types of solutions, the Keggin ion Al cluster is a minority species or totally absent. The typical 1.8–1.9 nm spacing is only obtained after washing. The quality of the pillared material can be judged from its thermal stability, its surface area, and the width of the d001 line before and after pillaring. The width should not exceed 0.3 nm before calcination and 0.5 nm after calcination. The latter criterion reflects the importance of the crystallinity of the parent clay for successful pillaring. Pillaring in concentrated conditions occurs by a combination of ion exchange and precipitation of Al and gives materials that exhibit poor thermal stability.

Key Words: Aluminium • Hectorite • Laponite • Pillaring • Saponite

Clays and Clay Minerals; October 1993 v. 41; no. 5; p. 598-607; DOI: 10.1346/CCMN.1993.0410510
© 1993, The Clay Minerals Society
Clay Minerals Society (www.clays.org)