Chemical Characterization, Structural Features, and Thermal Behavior of Sodium and Hydrogen Octosilicate

G. Borbély, H. K. Beyer, H. G. Karge, W. Schwieger, A. Brandt and K.-H. Bergk
Central Research Institute of Chemistry of the Hungarian Academy of Sciences, Budapest, Hungary
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin, Germany
Sektion Chemie, WB Technische Chemie, Martin-Luther-Universität, Halle, Germany

Abstract: The chemical composition and the thermal behavior of sodium and hydrogen octosilicate was studied by chemical and thermal analysis, infrared (IR), magic-angle-spinning nuclear magnetic resonance (MAS-NMR) spectroscopy, and X-ray diffractometry. Both compounds are layer silicates with basal spacings of 11.10 and 7.38 Å, respectively. In both forms the ratio of Q4 silicon (connected via oxygen bridges with four silicon atoms) to Q3 silicon (connected with only three other Si atoms) is 1. At least a small part of the Q4 silicon can be substituted by aluminum. Elimination of water coordinated to the cations in sodium octosilicate results in a concomitant structural collapse. Replacement of the sodium ions by protons affects the atomic arrangement in the sheets only to a minor degree, but results in a decrease of the periodicity along the crystallographic c axis. Upon heat treatment an endothermal structural rearrangement occurs at about 360 K as revealed by significant changes of the IR and 29Si MAS-NMR spectra. Reexchange with Na ions largely, but not completely, restores the structure of the parent octosilicate.

The X-ray diffraction pattern of sodium octosilicate was indexed in the monoclinic system with a = 7.345 Å, b = 12.74 Å, c = 11.25 Å and β = 99.3°. Based on conclusions drawn from the results of the present study, the X-ray pattern of hydrogen oclosilicate was tentatively indexed in the monoclinic system with a = 7.345 Å, b = 12.74 Å, c = 8.51 Å and β = 119.8°.

Key Words: Octosilicate • Sheet silicates • MAS-NMR spectroscopy • Thermal behavior

Clays and Clay Minerals; October 1991 v. 39; no. 5; p. 490-497; DOI: 10.1346/CCMN.1991.0390504
© 1991, The Clay Minerals Society
Clay Minerals Society (www.clays.org)