Interaction of Phenamiphos with Montmorillonite

J. Maza Rodríguez, A. Jiménez López and Sebastián Bruque
Departamento de Química Inorgánica, Universidad de Málaga Apartado 59, 29071 Málaga, Spain

Abstract: Phenamiphos interacted with homoionic montmorillonites of Ca2+, Mn2+, Co2+, and Ni2+ to form interlayer complexes having basal spacings of about 16.5/ Å. In the infrared spectra, the ν-PO bands were displaced towards lower frequencies suggesting that this group interacted with the exchange cations. Moreover, a small shoulder at 1600 cm−1 indicated the partial protonation of the phenamiphos. After heating the complexes to 110°, 160°, and 200°C, however, the bands corresponding to δ-NH2+ and ν-NH intensified because of increased protonation, whereas the ν-PO bands had the same intensity as in pure phenamiphos. The fundamental implication of these observations is that phenamiphos interacts with exchange cations through molecules of coordinated water, possibly by means of the P=O group.

Key Words: Infrared spectroscopy • Montmorillonite • Organophosphorus compound • Pesticide • Phenamiphos • Protonation

Clays and Clay Minerals; June 1988 v. 36; no. 3; p. 284-288; DOI: 10.1346/CCMN.1988.0360311
© 1988, The Clay Minerals Society
Clay Minerals Society (www.clays.org)