Natural Ammonium Illites from Black Shales Hosting a Stratiform Base Metal Deposit, DeLong Mountains, Northern Alaska

Edward J. Sterne1, Robert C. Reynolds Jr. and Half Zantop
Department of Earth Sciences, Dartmouth College, Hanover, New Hampshire 03755
1 Present address: Amoco Production Company (USA), Amoco Building, 1670 Broadway, Denver, Colorado 80202.

Abstract: Naturally occurring ammonium illites have been discovered in black shales surrounding a stratiform base metal deposit in the DeLong Mountains, northern Alaska. Infrared spectra of the samples exhibit pronounced absorption at 1430 cm−1, the resonant-banding frequency for NH4+ coordinated in the illite interlayer. X-ray powder diffraction characteristics of the ammonium illites include an expanded d(001) spacing, with values as large as 10.16 Å, and ratios for I001/I003 and I002/I005 of about 2. Infrared analyses of physical mixtures of NH4Cl with a standard illite, and comparisons with synthetic ammonium micas indicate significant substitution (>50%) of NH4+ for K+ in the illite interlayer position. Nitrogen determinations on two ammonium illites after removal of carbonaceous matter gave values of 1.48 wt. % NH4+ and 1.44 wt. % NH4+. A survey of more than 150 different shale horizons indicates that the NH4+ content of the illites increases in proximity to the stratiform base metal mineralization.

Key Words: Ammonium • Black shale • Illite • Infrared spectroscopy • Nitrogen • X-ray powder diffraction

Clays and Clay Minerals; June 1982 v. 30; no. 3; p. 161-166; DOI: 10.1346/CCMN.1982.0300301
© 1982, The Clay Minerals Society
Clay Minerals Society (www.clays.org)