Characterization of Adsorbed Iron in Montmorillonite by Mössbauer Spectroscopy1

A. Diamant, M. Pasternak and A. Banin
Department of Physics and Astronomy, Tel Aviv University, Ramat Aviv, Israel
Department of Soil and Water Sciences, The Hebrew University of Jerusalem, Rehovot, Israel
1 Sponsored in part by International Atomic Energy grant 2472/RB and by Ramot, the Tel Aviv University Authority for Applied Research and Industrial Development.

Abstract: The Mössbauer effect of Fe57 was used to probe and characterize iron ions adsorbed on the interlayer surfaces of montmorillonite. Measurements were performed with Fe- and Ca-saturated montmorillonites. At 210°K the intensity of the Fe2+ line was greatly reduced, apparently due to the melting of interlayer water. Neither the structural Fe2+ in Ca-montmorillonite nor the adsorbed Fe3+ in Fe-montmorillonite were affected by the melting process. From the temperature dependence of the absorption intensity, the effective Debye temperature of all the iron species appears to be approximately the same (θD = 189 ± 5°K). This result allowed for an accurate determination of the population of Fe2+/Fe3+ in various samples.

Key Words: Debye temperature • Iron • Montmorillonite • Mössbauer spectroscopy • Water

Clays and Clay Minerals; February 1982 v. 30; no. 1; p. 63-66; DOI: 10.1346/CCMN.1982.0300108

Clay Minerals Society (www.clays.org)