Reaction of Hydroxy-Bismuth Polycations with Montmorillonite

Shoji Yamanaka, Gunji Yamashita and Makoto Hattori
Department of Applied Chemistry, Faculty of Engineering Hiroshima University, Hiroshima, 730 Japan

Abstract: Interlayer sodium ions of montmorillonite were exchanged with hydroxy-bismuth polycations which were prepared from bismuth perchlorate solutions by the addition of NaOH. Assuming the charge density of the silicate layer to be unchanged, the compositions of the polycations involved in the exchange can be estimated from the amount of bismuth taken up by the montmorillonite and from the ignition loss between 110° and 800°C. The derived compositions are near [Bi6(OH)16]2+ irrespective of the ratio of OH:Bi in the perchlorate solution. The basal spacing of the hydroxy-bismuth montmorillonites is about 16 Å at 110°C, which corresponds to that of hydroxy-chromium montmorillonite having a high surface area of about 250 m2/g. The surface areas of the hydroxy-bismuth montmorillonites, however, are less than 80 m2/g.

Key Words: Bismuth • Cation exchange • Hydrolysis • Hydroxy-bismuth • Montmorillonite • Surface area

Clays and Clay Minerals; August 1980 v. 28; no. 4; p. 281-284; DOI: 10.1346/CCMN.1980.0280406
© 1980, The Clay Minerals Society
Clay Minerals Society (www.clays.org)