The Exothermic Reaction of Metakaolinite in the Presence of Mineralizers. Influence of Crystallinity

M. Bulens* and B. Delmon
Groupe de Physico-Chimie Minérale et de Catalyse, Place Croix du Sud 1, 1348 Louvain-la-Neuve, Belgium
* Aspirant, Fonds National Belge de la Recherche Scientifique.

Abstract: This paper presents further results concerning the nature of the exothermic reaction of meta-kaolinite near 950°C. In a previous work (Lemaitre et al., 1975), we proposed that the exothermic effect had a double origin: (a) direct formation of mullite, promoted by CaO and (b) formation of a segregated spinel-type phase, i.e. γ-Al2O3, promoted by MgO.

In this paper, we examine the influence of a further parameter on the reaction sequence, namely the crystallinity of the starting kaolinite as defined by Hinckley's index (c.i.; Hinckley, 1963). By combining X-ray and DTA techniques it is shown that the direct mullite formation path (a) occurs readily at 900°C in well-ordered kaolinite, but not in poorly ordered samples, even when fired with CaO. On the other hand, path (b) can be promoted in all samples using MgO as a mineralizer. When the indirect reaction path (b) occurs, a second exothermic effect is observed at approximately 1200°C indicating secondary mullite formation by recombination of segregated silica and alumina phases. This effect occurs in poorly ordered kaolinites even in the presence of CaO [path (a) promotor] indicating that path (b) is the most probable reaction mechanism in very disordered kaolinites.

Clays and Clay Minerals; August 1977 v. 25; no. 4; p. 271-277; DOI: 10.1346/CCMN.1977.0250404
© 1977, The Clay Minerals Society
Clay Minerals Society (www.clays.org)