Change of b-Dimension with Swelling of Montmorillonite

Israela Ravina and Philip F. Low
Faculty of Agricultural Engineering, Technion-Israel Institute of Technology, Haifa, Israel
Department of Agronomy, Purdue University, Lafayette, Indiana 47907, U.S.A.

Abstract: The effect of swelling on the b-dimension of Na-saturated, Upton, Wyoming montmorillonite was re-examined using powdered silicon as an internal standard. After being corrected with reference to the internal standard, the b-dimension did not increase through the entire range of swelling as reported previously. It increased up to a water content of ∼3.0 g/g montmorillonite and remained constant thereafter. However, the diffraction peak of the internal standard shifted towards lower angles at higher water contents. This shift was attributed to a relaxation of the wetter samples away from the knife edge of the diffractometer. Presumably, a similar relaxation occurred in the earlier study and was responsible for the apparent increase in b-dimension at water contents above ∼3.0 g/g.

The b-dimension of Upton montmorillonite saturated with different cations was determined using powdered silicon and a colloidal quartz impurity as internal standards. The water content at maximal swelling decreased as the b-dimension increased.

Clays and Clay Minerals; July 1977 v. 25; no. 3; p. 201-204; DOI: 10.1346/CCMN.1977.0250305
© 1977, The Clay Minerals Society
Clay Minerals Society (www.clays.org)