Polyelectrolyte Reinforced Aerogels of Clays—Application as Chromatographic Adsorbents*

H. van Olphen
Shell Development Company, Houston, Texas
* Published by permission of Shell Development Company (A Division of Shell Oil Company), Exploration and Production Research Division, Houston, Texas. Publication No. 472.
Present address: National Academy of Sciences, National Research Council, Washington, D.C.

Abstract: Aerogels of clays can be prepared by freeze-drying of clay water gels. The mechanical strength of the aerogels is improved by the addition of water-soluble polyelectrolytes to the hydrogels.

The porosity of the powdered aerogels can be adapted to the requirements for adsorbents in gas chromatography by compounding the hydrogels with suitable amounts of polyelectrolytes. Simultaneously, the surface of the clay may be modified by adsorption of polar or cationic organic compounds in order to achieve specific chromatographic separations.

Because of the toughness of the clay-polyelectrolyte aerogels, they can be rolled out to thin sheets which may be applied as chromatographic papers.

Clays and Clay Minerals; 1967 v. 15; no. 1; p. 423-435; DOI: 10.1346/CCMN.1967.0150142
© 1967, The Clay Minerals Society
Clay Minerals Society (www.clays.org)