Statistical Distribution Patterns of Particle Size and Shape in the Georgia Kaolins

Robert F. Conley
Georgia Kaolin Research Laboratories, Elizabeth, New Jersey

Abstract: High resolution electron micrographic techniques have been employed for surveying the size and shape distributions of kaolinite particles, both plates and stacks, from well-crystallized Georgia deposits.

Both size and shape follow typical, positively-skewed, frequency distributions. Particle thicknesses among plates appear quantized, dominantly as hoxalaminae and subordinately as trilaminae of the basic c-axis dimension in the unit cell. Specimens subjected to severe shear and attrition show intermediate values of thickness, i.e. 3n + 1 and 3n + 2. Profile studies on kaolinite stacks reval integral platelet units whose distribution in thickness corresponds to that of individual plates.

Energy calculations for fracture (cleavage ‖ to c-axis) and delamination (cleavage ⊥c-axis) processes indicate that hydrokinetic cleavage in nature should result in particles having an aspect ratio distribution peaking near 6 : 1. The dominance of stacks above 10 µ is suggestive of in situ weathering. Experimental shear measurements correlate well with these proposals.

Sedimentation studies with clays of various shapes and distributions were performed in a variety of aqueous media, including sea water. Sediment volume data, microscopic observations, and theoretical packing calculations are compared with the several mechanisms proposed for plate-stack genesis.

Clays and Clay Minerals; 1966 v. 14; no. 1; p. 317-320; DOI: 10.1346/CCMN.1966.0140128
© 1966, The Clay Minerals Society
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