Cesium Sorption Reactions as Indicator of Clay Mineral Structures

Tsuneo Tamura
Health Physics Division, Oak Ridge National Laboratory,1 Oak Ridge, Tennessee 1 Operated by Union Carbide Corporation for the U.S. Atomic Energy Commission.

Abstract: At low cesium ion concentrations extremely high selectivities for cesium are exhibited by layer lattice silicates with unexpanded 10 Å c-spacing. The total amount of cesium which can be sorbed by these minerals depends on the edge area and the exchange capacity. At a concentration of 10−5 meq of cesium and 5 meq of sodium, a sample of biotite representing less than 0.025 meq of exchange capacity sorbed over 90 per cent of the cesium and a hydrobiotite with 50 percent vermiculite and representing 1.0 meq of exchange capacity sorbed 80 percent of the cesium.

After heating bentonites to 500–700°C more cesium is sorbed from solutions containing high sodium concentrations by the heated bentonite than the original material. The change in the amount of cesium sorbed as a result of heating may be a useful property for detecting the presence of montmorillonite in mixed or interlayered mineral systems. Lattice expansion of biotite results in improved cesium sorption; this behavior is due to generation of sufficient favorable exchange sites to offset the loss of edges with favorable 10 Å spacing.

Clays and Clay Minerals; 1961 v. 10; no. 1; p. 389-398; DOI: 10.1346/CCMN.1961.0100135
© 1961, The Clay Minerals Society
Clay Minerals Society (www.clays.org)